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Research Journal of Science and Technology
Year : 2015, Volume : 7, Issue : 4
First page : ( 230) Last page : ( 233)
Print ISSN : 0975-4393. Online ISSN : 2349-2988.
Article DOI : 10.5958/2349-2988.2015.00033.9

Metal Catalyzed Oxidation of L-Arginine by Alkaline KMnO4: A Kinetic and Mechanistic Study

Panda Sandhyarani1,*, Satpathy M.2, Mohanty P.1

1Utkal University, Vani Vihar, Bhubaneswer, Odisha

2Govt Girls Polytechnic, Byron Bazar, Raipur, C.G

*Corresponding Author E-mail: mrutunjaya2003@gmail.com

Online published on 8 December, 2015.

Abstract

Metal catalysed oxidation of Arginine by Potassium permangate in highly basic medium were studied spectrophotometrically over the range 20< t< 30°C, I= 0.5, 2x10−4 < oxidant < 9x10−4 mol/dm3, 1x10−7< catalyst< 5x10−7 mol/dm3. The reaction is 1st order with respect to the oxidant, substrate and catalyst. The activation parameters were calculated and tabulated.

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Keywords

KMnO4, Arginine, Ruthenium catalyst.

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