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Research Journal of Pharmacy and Technology
Year : 2017, Volume : 10, Issue : 9
First page : ( 2949) Last page : ( 2951)
Print ISSN : 0974-3618. Online ISSN : 0974-360X.
Article DOI : 10.5958/0974-360X.2017.00522.4

Growth of (e)-(3-chloro-2-nitroprop-1-enyl)benzene using Nitro Olefin derivatives Crystal

Sivakumar M.N.1,*, Vidya A.2

1Assistant Professor, Department Chemistry, AMET University, Kanathur, Chennai, 603 112, India

2Assistant Professor, Department of Chemistry, Madras University

*Corresponding Author E-mail: nitrosiva@yahoo.co.in

Online published on 16 May, 2018.

Abstract

For the first time Baylis-Hillman adducts derived from nitro olefins have been conveniently transformed into a novel class of building blocks, (E)-(3-chloro-2-nitroprop-1-enyl)benzene. The large second order optical nonlinearities, short transparency cut-off wavelength and stable physiochemical performance, which are needed in the realization of most of the recent electronic applications, are also considered in the present study.

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Keywords

Baylis-Hillman reaction, nitro olefin, (E)-2-nitro-3-phenylprop-2-en-1-ol, TiCl4, THF and (E)(3-chloro-2-nitroprop-1-enyl)benzene.

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