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Research Journal of Pharmacy and Technology
Year : 2017, Volume : 10, Issue : 11
First page : ( 3974) Last page : ( 3980)
Print ISSN : 0974-3618. Online ISSN : 0974-360X.
Article DOI : 10.5958/0974-360X.2017.00722.3

Synthesis, solubility and thermal behavior of novel Diamino-diphenyl methane and caprolactam based different polyimide matrix for antibacterial applications

Revathi R.1, Anandhavelu S.1, Dolli H.1, Murugavelu M.1, Jeevarose K.1, Alagar M.2,*

1Vel Tech Multi Tech Dr. Rangarajan Dr. Sakunthala Engineering College, Department of Chemistry, Avadi, Chennai, 600 062, India

2Centre of Excellence for Advanced Material Manufacturing, Processing and Characterization (CoExAMMPC), VFSTR University, Vadlamudi, Guntur-522 213, India

*Corresponding Author E-mail: mkalagar@yahoo.com, muthukaruppanalagar@gmail.com

Online published on 26 March, 2018.

Abstract

Novel polyimides (PIs) are synthesized by N, N ‘-(4, 4′-methylene bis (4, 1-phenylene)) bis (6-aminohexanamide) (CPA), pyromellitic dianhydride (PI-1), benzophenone dianhydride (PI-2), naphthalene dianhydride (PI-3), and perylene dianhydride (PI-4) in presence of 1-methyl-2-pyrrolidone (NMP) medium using thermal imidization method. As-synthesized polyimides were physicochemical characterization done by FTIR, XRD, TGA, DSC and the surface morphology and particle in size of polyimides by SEM analysis. The PIs synthesized in the present work exhibit good solubility in organic solvents such as NMP, dimethylformamide (DMF), and dimethyl sulfoxide (DMSO). The PI-4 based imide possesses better solubility with the highest glass transition temperature value of 206° C, highest char yield of 31.5%, and improved antibacterial activity than those of other PIs. Furthermore, the good solubility and thermal stability make them also useful for aerospace and industrial applications.

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Keywords

Caprolactam, DDM, polyimide, thermal behaviour, morphological behaviour, antibacterial activity.

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