Synthesis of Copolymers of Acrylamide and Acrylonitrile via Redox Polymerization Bhadani Reena1,*, Bhadani S. N.2 1Department of Chemistry, Ranchi Women's College, Ranchi 2P. G., Department Of Chemistry, Ranchi University, Ranchi *Corresponding Author E-mail: rbhadani04@gmail.com
Online published on 31 December, 2015. Abstract The redox copolymerization of acrylonitrile with acrylamide in N, N-dimethylformamide (DMF) containing K2S2O8 and AgNO3 was carried out. The resulting copolymers were soluble in this solution. A white floppy mass was obtained, when poltmerizing solution was poured in cold methanol. The copolymers were formed taking different feed ratios of monomers and concentrations of the initiators at 60°C. As the concentration of acrylamide increased in the feed ratio, copolymer yields consierably increased. The copolymerization was completely inhibited by 2, 2-diphenyl-1-picrylhydrazyl suggesting a free radical reaction. Top Keywords Redox polymerization, acrylonitrile, acrylamide and copolymers. Top |