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Asian Journal of Research in Chemistry
Year : 2015, Volume : 8, Issue : 1
First page : ( 51) Last page : ( 55)
Print ISSN : 0974-4169. Online ISSN : 0974-4150.
Article DOI : 10.5958/0974-4150.2015.00011.5

Study of Binary Complex formation of Fe (III) with 3-Hydroxy-3-(phenyl)-1-2, 4Dimethyl Phenyl Triazene

Choubisa Naresh Kumar*, Panwar Ashok, Regar Mangilal, Singh G.P., Dashora Rekha, Chauhan R.S., Goswami A.K.

Coordination Chemistry Laboratory, Department of Chemistry, University College of Science, Mohanlal Sukhadia University, Udaipur-313001, Rajasthan, India

*Corresponding Author E-mail: choubisan@gmail.com

Abstract

The present paper reports synthesis, characterization, spectrophotometric studies and activity prediction of HPMPT with Fe (III) complexes. It was observed that Fe (III) forms complex with HPMPT in 1:3 ratio at wavelength of 510 nm and between the pH range of 4.3–4.8. The molar absorptive and Sandell's sensitivity values are 52175 L mol−1 cm−1 and 1.32 ng cm−2 respectively. The study shows that metal chelates are better in activity as compared to their respective ligands. The results have been interpreted in terms of tables, figures and theories.

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Keywords

HPMPT, Spectrophotometric, Activity Prediction, PASS.

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