|
|
|
|
|
|
|
|
|
|
Solvent effect and Activation Parameters: A Kinetic Reaction of Ethyl Caprylate in Water-Acetone Media Singh A.K.* Teerthanker Mahaveer University, Moradabad, India *Corresponding Author E-mail: dr.anilkumarsingh2009@gmail.com
Online published on 19 February, 2022. Abstract The kinetic result of hydrolysis of Ethyl Caprlyate has been investigated at different composition of aqueous-organic solvent with Acetone (30-70% v/v) over the temperature range of 20 to 40°C. The calculated result follows second order kinetics and is observed that the rate decreases with increasing proportion of Acetone. This behavior is attributed electrostatic nature that various solvent-solute interaction in reaction media. Linear plots of Logk against water concentration shows that equilibrium shifted from dense form to bulky form. Iso-kinetic temperature has been determined with the help of slopes of (ΔH*) versus (ΔS*). Thermodynamic parameter has been calculated with the help of Wynne-Jones and Eyring equation. Top Keywords Ethyl Caprylate, Kinetics solvent effect, Acetone, Water, Activation parameter. Top | | | |
|
|
|
|
║ Site map
║
Privacy Policy ║ Copyright ║ Terms & Conditions ║
 ║
|
|
|
838,876,504 visitor(s) since 30th May, 2005.
|
|
All rights reserved. Site designed and maintained by DIVA ENTERPRISES PVT. LTD..
|
|
Note: Please use Internet Explorer (6.0 or above). Some functionalities may not work in other browsers.
|