[ij] [ij] [ij] 
Email id

Asian Journal of Research in Chemistry
Year : 2020, Volume : 13, Issue : 3
First page : ( 216) Last page : ( 218)
Print ISSN : 0974-4169. Online ISSN : 0974-4150.
Article DOI : 10.5958/0974-4150.2020.00041.3

Study of Solvent effect of Protic solvent on Solvolysis of Hexanoate ester and Activation parameters

Singh A. K.1,*, Tiwari L. K.2

1Department of Chemistry, Teerthanker Mahaveer University, Moradabad, India

2Dpartment of Mathematics, Teerthanker Mahaveer University, Moradabad, India

*Corresponding Author E-mail: anilkumar2_singh@yahoo.com

Online published on 10 August, 2020.


The kinetics of alkaline hydrolysis of propyl Hexanote has been studied as a base catalyst under second order reaction at the temperature range from 20 to 40°C. The reaction rate was measured volumetrically over a range of water-propanol mixed solvent(30–70% v/v).The reaction rate was found to be increased with increasing temperature at all composition of reaction mixture. Thermodynamic parameter was calculated. The non-linear increase in free energy with mole% suggests the specific salvation taking place in reaction media. The value of iso-kinetic temperature is more than 300 which indicates strong solvent-solute interaction in reaction media.



Propyl formate, kinetics, propanol, water, solvent effect.


║ Site map ║ Privacy Policy ║ Copyright ║ Terms & Conditions ║ Page Rank Tool
693,392,300 visitor(s) since 30th May, 2005.
All rights reserved. Site designed and maintained by DIVA ENTERPRISES PVT. LTD..
Note: Please use Internet Explorer (6.0 or above). Some functionalities may not work in other browsers.