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Asian Journal of Research in Chemistry
Year : 2019, Volume : 12, Issue : 4
First page : ( 203) Last page : ( 207)
Print ISSN : 0974-4169. Online ISSN : 0974-4150.
Article DOI : 10.5958/0974-4150.2019.00038.5

Synthesis, Crystal Structure, Spectral and Theoretical Studies of an New Organic-Inorganic Hybrid iron (II) Complex of Squarate Fe(C2O4).2H2O

Siham Sid1, Zenkhri Louiza1,*, Loubna Ben Amor1, Benouna Khalida1, Boutarfaia Ahmed2

1Univ Kasdi Merbah Ouargla, Chemistry Department, Faculty of Mathematics and Matter Sciences, BP 511 Route Ghardaia, Ouargla, Algeria-30 000

2Univ Mohammed Khider Biskra, Science of Matter Department, Faculty of Exact Sciences and Sciences of Nature and life, BP 145 RP. 00700, Biskra

*Corresponding Author E-mail: louizazenkhri@yahoo.fr

Online published on 19 December, 2019.


Complex of oxalate ion and divalent iron with general formula Fe(C2O4).2H2O has been prepared and characterized by spectral FT-IR, elemental analysis, powder X-ray diffraction, and computational studies was carried. The complex has distorted octahedral geometries with two bidentate oxalate and two water ligands. These calculations have provided the most stable conformations and the lower energies.



X rays diffraction, hyperchem, hybrid, oxalate, IR spectra.


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