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Asian Journal of Research in Chemistry
Year : 2018, Volume : 11, Issue : 2
First page : ( 369) Last page : ( 378)
Print ISSN : 0974-4169. Online ISSN : 0974-4150.
Article DOI : 10.5958/0974-4150.2018.00067.6

Kinetics and Mechanistic study of oxidation of L-Alanine by Using N-Bromophalimide in presence of Chloro-Complex of Pd (II) as Homogenous Catalyst in Aqueous Acetic acid medium

Gawai Jaishree1, Farooqui Mazahar2, Lawale Narayan3, Ubale Milind4,*

1Jawaharlal Nehru Engineering College, N-6 CIDCO, Aurangabad, India

2Dr. Rafiq Zakaria College for Women, Aurangabad, India

3Moreshwar Arts, Commerce and Science College, Bhokardan Dist Jalna, India

4Vasantrao Naik College, India

*Corresponding Author E-mail: drmilindubale@gmail.com

Online published on 2 June, 2018.

Abstract

Spectrophotometric study of oxidation of Palladium chloride catalyzed L-Alanine in aqueous acetic acid medium has been studied at different temperatures. Present research work focus on effect of various parameters on oxidation of L-Alanine. Parameters varies during the study of reaction is concentration of L-Alanine, Palladium chloride and effect of salts on oxidation phenomenon. As a conclusion oxidation reaction was found as first order reaction with respect to L Alanine, N bromopthalamide Palladium chloride, Perchloric acid and Kcl.

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Keywords

L-Alanine, NBP, Perchloric acid (HClO4), Mercuric Acetate (Hg(AO)2, Acetic acid (CH3COOH).

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