Research Journal of Science and Technology

  • Year: 2015
  • Volume: 7
  • Issue: 4

Metal Catalyzed Oxidation of L-Arginine by Alkaline KMnO4: A Kinetic and Mechanistic Study

1Utkal University, Vani Vihar, Bhubaneswer, Odisha

2Govt Girls Polytechnic, Byron Bazar, Raipur, C.G

Abstract

Metal catalysed oxidation of Arginine by Potassium permangate in highly basic medium were studied spectrophotometrically over the range 20< t< 30°C, I= 0.5, 2x10−4 < oxidant < 9x10−4 mol/dm3, 1x10−7< catalyst< 5x10−7 mol/dm3. The reaction is 1st order with respect to the oxidant, substrate and catalyst. The activation parameters were calculated and tabulated.

Keywords

KMnO4, Arginine, Ruthenium catalyst