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Research Journal of Pharmacy and Technology
Year : 2018, Volume : 11, Issue : 3
First page : ( 1065) Last page : ( 1070)
Print ISSN : 0974-3618. Online ISSN : 0974-360X.
Article DOI : 10.5958/0974-360X.2018.00199.3

Synthesis of new heterocyclic 1, 4-bis2-phenyl-2, 3-dihydrobenzo-1, 3oxazepine-4, 7-dionebenzene

Yasir Asstabraq Mohsin*, Waheeb Azal Shakir**

Department of Chemistry, Faculty of Science, AL-Muthanna University

*Corresponding Author E-mail: asstabraq@mu.edu.iq,

**azilshker@mu.edu.iq

Online published on 7 July, 2018.

Abstract

Through this research we have well prepared the new [1, 4-Bis(2-phenyl-2, 3-dihydrobenzo-1, 3-oxazepine-4, 7dione)benzene(Z2)]is a seven-member ring that contains nitrogen, oxygen. The first step, prepared schiff bases N-benzylidenephenylenediamine F1 were synthesized by the condensation of equimolar quantity of primary aromatic amines p-Phenylenediamine with benazldehyde. The second step, percyclic reactions, between imine groups of schiff base F1 as two-membered components and cyclic acid anhydride phathalic anhydride as five membered component in dry benzene, were carried out to the synthesis of 1, 3-oxazepine derivatives Z1. The third step, prepared schiffbasesF2 were synthesized by the condensation of equimolar quantity of primary aromatic amines Z1 by with benazldehyde. Finally, prepared 1, 3-oxazepine derivatives Z2 by percyclic reactions. This preparing compounds were monitored and characterized by melting points, TLC, 1H-NMR, and FT.IR spectroscopy.

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Keywords

Schiff base, Phathalic anhydride, Oxazepine.

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