(3.230.1.126)
Users online: 1533    [ij] [ij] [ij] 
Email id
 

Asian Journal of Research in Chemistry
Year : 2016, Volume : 9, Issue : 5
First page : ( 197) Last page : ( 199)
Print ISSN : 0974-4169. Online ISSN : 0974-4150.
Article DOI : 10.5958/0974-4150.2016.00033.X

Synthesis and Characterization of Mikanecic acid Diesters using NaH

Nandhikumar R.1,2,*, Subramani K.1,3

1R&D Centre, Bharathiar University, Coimbatore, Tamilnadu, India

2Global Institute of Engineering and Technology, Tamilnadu, India

3PG & Research, Department of Chemistry, Islamiah College, Vaniyambadi, Tamilnadu, India

*Corresponding Author E-mail: nandhikumar@gmail.com

Online published on 21 June, 2016.

Abstract

Catalysts are used to make changes easier in the organic synthetic mechanism. Catalysts are involved in the process of chemical changes by reducing time and making it faster to get things done. Catalysts play a vital role in organic synthesis with a novel method for the synthesis of a terpenoid, Mikanecic acid diester. In this research we are using NaH to synthesis Baylis-Hillman adducts (alkyl-3-hydroxy-2-methylenepropanoates reacts with aldehyde with a variety of acrylates catalyzed in presence of TiCl4). Mikanecic acid diesters obtained from 1, 3-butadiene-2-carboxylate of (Diels-Alder type) self-dimerization occur in the presence of different catalysts. The yield which we obtained is in good ratio.

Top

Keywords

Baylis-Hillman adducts, Mikanecic acid diester, NaH, THF.

Top

  
║ Site map ║ Privacy Policy ║ Copyright ║ Terms & Conditions ║ Page Rank Tool
452,192,823 visitor(s) since 30th May, 2005.
All rights reserved. Site designed and maintained by DIVA ENTERPRISES PVT. LTD..
Note: Please use Internet Explorer (6.0 or above). Some functionalities may not work in other browsers.