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Asian Journal of Research in Chemistry
Year : 2015, Volume : 8, Issue : 10
First page : ( 618) Last page : ( 624)
Print ISSN : 0974-4169. Online ISSN : 0974-4150.
Article DOI : 10.5958/0974-4150.2015.00098.X

Metal Catalyzed Oxidation of L-Isoleucine by Alkaline KMnO4: A Kinetic and Comparative Study

Panda Sandhyarani1,*, Satpathy M.2, Mohanty P.1

1Utkal University, Vani Vihar, Bhubaneswer, Odisha

2Govt Girls Polytechnic, Byron Bazar, Raipur, C.G

*Corresponding Author E-mail: mrutunjaya2003@gmail.com

Online published on 8 December, 2015.

Abstract

Metal catalysed oxidation of L-Isoleucine by Potassium permangate in highly basic medium were studied spectrophotometrically over the range 25< t< 35°C, I= 0.5, 2x10−4 < oxidant < 10x−4, 1x10−7< catalyst< 5x107.The reaction is 1st order with respect to the oxidant, substrate and catalyst. The activation parameters were calculated, compared and tabulated.

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Keywords

KMnO4, Isoleucine, Chromium, Ruthenium.

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