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Asian Journal of Research in Chemistry
Year : 2017, Volume : 10, Issue : 5
First page : ( 651) Last page : ( 656)
Print ISSN : 0974-4169. Online ISSN : 0974-4150.
Article DOI : 10.5958/0974-4150.2017.00110.9

Percentage Distribution of Ni(II) in Biligand Systems Involving Some Biologically Significant Ligands

Upadhyaya Neerja1,*, Dwivedi K.2, Ahuja R. Nair3

1S.S. Jain Subodh Girls College, Sanganer, Jaipur, Rajasthan, India-302011

2School of Studies in Chemistry, Jiwaji University, Gwalior, Madhya Pradesh, India-474011

3Vijya Raje Govt. Girls P. G. College, Morar, Gwalior, M.P., India-474006

*Corresponding Author E-mail: upadhyayaneerja@gmail.com

Online published on 26 March, 2018.

Abstract

Bioaccumulation of metal ions involves formation of complexes. Solution studies on biomimmetic systems were carried out. Results obtained for nickel(II), L-tyrosine, L-alanine, L-phenylalanine, L-aspartic acid and Lglutamic acid are being presented in this piece of work. All these ligands are physiologically related to each other and are directly or indirectly involved in nerve transduction. These ligands coordinate with metal ions. Equimolar ternary systems involving L-tyrosine were investigated in aqueous medium at different temperatures and ionic strengths in order to find out K, enthalpy, entropy and free energy change of formation of biligand complexes. pH-metric data was subjected to SCOGS Computer program to refine the values as calculated by the method of Martell and Chaberek. Percentage distribution of metal ion over the entire experimental pH range was obtained.

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Keywords

biligand complexes, ionic strength, percentage distribution.

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