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Asian Journal of Research in Chemistry
Year : 2017, Volume : 10, Issue : 2
First page : ( 131) Last page : ( 134)
Print ISSN : 0974-4169. Online ISSN : 0974-4150.
Article DOI : 10.5958/0974-4150.2017.00021.9

Stability Constants of Mixed Ligand Complexes of Transition Metal(II) ions with 1-[(1E)-N-(2, 6-dichlorophenyl)ethanimidoyl]naphthalen-2-ol and 4-bromo-2-{(E)-[(2, 3-dimethylphenyl)imino]methyl}phenol.

Mapari Atmaram Kacharu*

Department of Chemistry, Ramnarain Ruia College, Matunga (E), Mumbai-400019, Maharashtra, India

*Corresponding Author E-mail: akmapari@gmail.com

Online published on 17 July, 2017.

Abstract

Binary and ternary complexes of the type M-Y and M-X-Y [M = Co(II), Ni(II), Cu(II) and Zn(II); X = 4-bromo2-{(E)-[(2, 3-dimethylphenyl)imino]methyl}phenol and Y= 1-[(1E)-N-(2, 6-dichlorophenyl)ethanimidoyl] naphthalen-2-ol] have been examined pH-metrically at 27 ± 0.5°C and at constant ionic strength, μ = 0.1 M (KCl) in 75: 25 (v/v) 1, 4-dioxne-water medium. The stability constants for Binary (M-Y) and ternary (M-X-Y) systems were calculated.

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Keywords

Binary complexes, Ternary complexes, Mixed ligand, Stability constant.

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